Deposition and flocculation of asphaltenes from crude oils

Abstract

ABSTRACTA crude oil has four main constituents: saturates, aromatics, resins, and asphaltenes. The asphaltenes in crude oil are the most complex and heavy organic compounds. The classic definition of asphaltenes is based on the solution properties of petroleum residuum in various solvents. Asphaltenes are a solubility range that is soluble in light aromatics such as benzene and toluene, but are insoluble in lighter paraffins. The particular paraffins, such as n-pentane and n-heptane, are used to precipitate asphaltenes from crude oil. Deposition of asphaltenes in petroleum crude and heavy oil can cause a number of severe problems. The precipitation of asphaltene aggregates can cause such severe problems as reservoir plugging and wettability reversal. Asphaltenes can precipitate on metal surface. Cleaning the precipitation site as well as possible appears to slow reprecipitation. To prevent deposition inside the reservoir, it is necessary to estimate the amount of deposition due to various factors. The processes can be changed to minimize the asphaltene flocculation, and chemical applications can be used effectively to control depositions when process changes are not cost effective. Asphaltene flocculation can be controlled through better knowledge of the mechanisms that cause its flocculation in the first place. The processes can be controlled to minimize the asphaltene flocculation, and chemical applications can be used effectively to control depositions when process changes are not cost effective.