Abstract
Abstract Effects of enantioselective interactions on redox reactions of chiral molecules were studied using Au single crystal electrodes modified with amino acids. The redox peak current densities of R(+)- or S(−)-N, N-dimethyl-1-ferrocenylethylamine on Au(111) modified with L- or D-homocysteine (L-/D-Hcy) depended on the combination of these chiralities. Hcy/Au(100) showed no dependence on redox peak current densities. The difference in the molecular arrangement of Hcy between Au(111) and Au(100) greatly affects enantioselective redox reactions at the electrode interface.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
