Abstract
The electron longitudinal spin relaxation time of a nitroxide radical dissolved in toluene, has been measured in the concentration range 2.5 × 10-4┌5 M The use of a new electron spin resonance technique with double transverse irradiation and longitudinal detection, allowed these extended measurements. The experimental values, which vary by orders of magnitude in the samples studied, are in good general accord with theory. The respective weights of different relaxation mechanisms have been evaluated at concentrations which it had not proved possible to study with other techniques.
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