Abstract
Using the1N NMR method of frozen suspensions, we studied the structure of hydrate shells in powders of dioxinaphthalenes (DON). We show that for the 1.5-DON isomer, which has a high ice-forming activity, on a DON/ice interface a thinner (in comparison with the nonactive 2,6- and 2,7-DON isomers) layer of water is formed which is bound with the surface. Moreover, in frozen, 1,5-DON suspensions a great quantity of ice is present, which has an extremely high mobility of water molecules.
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