Dependence of resistivity of natural rock samples on humidity

Abstract

Rock resistivity measurements under non-wet conditions are essential for interpreting subsurface shallow resistivity structure. This study investigated the resistivity of rock samples collected from several locations around the Nakadake craters of Aso Volcano, Japan. The resistivity of rock samples exhibited a logarithmically linear relationship with changes in absolute humidity, corresponding to possible seasonal variations and correlating with the porosity of rocks. As the samples maintained an identical cylindrical shape and size, the observed variations in humidity were unrelated to the external surface area but were caused by the internal pore structure of rocks. Furthermore, the external surface area of homogeneous granite was artificially varied using slits and its measured resistivity did not vary in the presence of slits. The measured distribution of electrical potential was well explained by a homogeneous model, and less so by a two-layer model, indicating that the region of resistivity change was not restricted to the surface of the sample, but rather covered the entire sample. Further, changes in resistivity in response to absolute humidity were caused by the adsorption of water molecules onto minerals at internal pore surfaces, as evidenced by the measured temporal scale of resistivity change based on a simple concentration–diffusion process of gaseous water molecules caused by humidity changes in the external environment. These findings imply significant variations in the resistivity of shallow subsurfaces owing to humidity changes; thus, the consideration of humidity is important for the interpretation of subsurface shallow resistivity structures.