Abstract
A computer simulation technique (Monte Carlo method) using 256 particles was carried out to determine the local compositions of the “LB 2” model mixture, and the local composition ratio τ ij (r) was found to be density dependent. A mole fraction dependence was introduced in this work instead of the density dependence and used to develop the Wilson type and Renon-Prausnitz type mixing rules for the parameters “a” and “b” of the van der Waals equation. However, the calculated vapor-liquid equilibrium values indicate that strong density dependence of local composition mixing rules is not generally necessary in VLE calculations using cubic equations of state.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
