Abstract
AbstractThe excess molar volumes (VE) and the deviations in molar refraction (ΔR) at 298.15 K were determined for the binary systems {diisopropyl ether (DIPE) + 1‐propanol}, {Tert‐amyl methyl ether (TAME) + methanol}, {DIPE + trihexyltetradecylphosphonium bis(2,4,4‐trimethylpentyl)phosphinate ([P666,14][TMPP])}, {TAME + [P666,14][TMPP]}, {methanol + [P666,14][TMPP]} and {1‐propanol + [P666,14][TMPP]} using a digital vibrating‐tube densimeter and a precision digital refractometer. The VE and ΔR were correlated with the Redlich–Kister equation for binary systems. In addition, the ternary VE and ΔR data at 298.15 K were predicted for the ternary systems {DIPE + 1‐propanol + [P666,14][TMPP]} and {TAME + methanol + [P666,14][TMPP]} by using the binary contribution model of Radojkovič with correlated sub‐binary Redlich–Kister parameters. © 2011 Canadian Society for Chemical Engineering
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