Abstract
A model of a chemically reacting fluid in a slit-like pore is studied. The density profiles of the fluid particles inside the pore, the adsorption isotherms, and the solvation force acting between the walls of the pore are investigated within the integral equation method. The Percus-Yevick and hypernetted chain approximations for the fluid particle-pore correlations are used. The model for the bulk chemically reacting fluid is that proposed by Cummings and Stell for a mixture of overlapping hard spheres. The investigations are performed for pores of different width, at different densities of the bulk fluid which is in an equilibrium with the confined fluid and for different degrees of bulk fluid association. The bulk fluid is described by using the Percus-Yevick approximation. A wide range of thermodynamic states and different bonding lengths between the reactants are investigated. It is shown that the effect of a chemical reaction in the bulk fluid produces qualitative changes in the behaviour of the den...
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