Abstract

The energy spectrum of low-frequency vibrational modes in amorphous polyisobutylene doped with chromophore tetra-tert-butylterrylene molecules has been measured. The technique for measuring the spectra of vibrational modes in solid amorphous media by single-molecule spectroscopy is described. The measured spectrum is compared with the data on the density of vibrational states (bosonic peak) in pure polyisobutylene, which were obtained by inelastic neutron scattering. It is shown that incorporation of small amounts of tetra-tert-butylterrylene into polyisobutylene did not significantly change the low-temperature vibrational dynamics of the matrix.

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