Density of Fe‐Ni‐C Liquids at High Pressures and Implications for Liquid Cores of Earth and the Moon

Abstract

AbstractThe presence of light elements in the metallic cores of the Earth, the Moon, and other rocky planetary bodies has been widely proposed. Carbon is among the top candidates in light of its high cosmic abundance, siderophile nature, and ubiquity in iron meteorites. It is, however, still controversial whether carbon‐rich core compositional models can account for the seismic velocity observations within the Earth and lunar cores. Here, we report the density and elasticity of Fe90Ni10‐3 wt.% C and Fe90Ni10‐5 wt.% C liquid alloys using synchrotron‐based X‐ray absorption experiments and first‐principles molecular dynamics simulations. Our results show that alloying of 3 wt.% and 5 wt.% C lowers the density of Fe90Ni10 liquid by ∼2.9–3.1% at 2 GPa, and ∼3.4–3.6% at 9 GPa. More intriguingly, our experiments and simulations both demonstrate that the bulk moduli of the Fe‐Ni‐C liquids are similar to or slightly higher than those of Fe‐Ni liquids. Thus, the calculated compressional velocities (vp) of Fe‐Ni‐C liquids are higher than that of pure Fe‐Ni alloy, promoting carbon as a possible candidate to explain the elevated vp in the Earth's outer core. However, the values and slopes of both density and vp of the studied two Fe‐Ni‐C liquids do not match the outer core seismic models, suggesting that carbon may not be the sole principal light element in Earth's outer core. The high vp of Fe‐Ni‐C liquids does not match the presumptive vp of the lunar outer core well, indicating that carbon is less likely to be its dominant light element.