Abstract
Infrared integrated intensities, measured for vibration-rotation bands of C2D2, N2O and CO2 compressed with argon and krypton, are found to be a linear function of the rare gas density up to 250 amagat. Above this density and up to 468 amagat, a departure from linearity is observed in the study of the v 3 band of CO2 in krypton. An attempt of interpretation is made considering induced and local field effects. It is shown that the latter is largely predominant and able to explain the observed density dependence. Moreover questions concerning the size of the cavity intervening in the model are discussed. It is concluded that this size is independent from the density of the medium.
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