Abstract

The present work is devoted to the analysis of polarization effects in atomic systems of the argon type. Special attention is given to the manifestation of the polarizabilities of two particles in the density dependence of the dielectric permittivity of a system and its effective molecular polarizability. It is shown that the effective polarizability of a molecule in the liquid state of a system is mainly caused by deviation of the molecular distribution in the first coordination layer from the spherical one. Due to this, the atomic polarizability inherent to rarefied gas increases practically twice near the triple point. The interconnection between the atomic polarizability and the proper volume of an atom is discussed in detail. It is established that the optimal size of an atom follows from the kinematic shear viscosity measurements.

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