Abstract
Densities of aqueous calcium chloride solutions are reported for molalities up to 6.4 mol-kg−1 at temperatures from 50 to 200°C and at 20.27 bar. Apparent molar volumes calculated from experimental densities were fitted to the equations of Rogers and Pitzer, and the temperature dependence of the Pitzer parameters were obtained. The standard deviation of fit for the apparent molar volumes is 0.21 cm3-mol−1 from 50 to 200°C at 20.27 bar.
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