Abstract
Several nucleophiles were separately treated with methyl and phenyl 2,3-anhydro-4,6- O-benzylidene-3-deoxy-3-nitro-β- d-allopyranoside, to give 2-substituted aldos-3-ulose derivatives. In the latter case, the subsequent β-elimination of the aglyconic phenyl group always occurred to afford the corresponding glycal. Reaction mechanisms thereof are also discussed.
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