Abstract

Nine experimental delta-ferritic steels have been examined as potential low expansion heat-resistant steels for use in fossil fuel power generation, nuclear power generation, nuclear process heat plants and coal gasification plants. The steels contain 10 to 14 pct Cr and 2 to 6 pct Mo, with additions of columbium, titanium, vanadium, aluminum and boron. Room-temperature tensile properties and oxidation resistance of all steels were determined. Selected steels were aged for 1000 h at 760 °C (1400 °F) and subjected to elevated temperature tensile tests at the aging temperature. Creep-rupture properties of selected steels were determined at 760 and 815 °C (1400 and 1500 °F). Extensive metallographic and phase identification studies were conducted. Of the two steels tested for creep-rupture strength, the 10Cr-6Mo-0.5Cb steel, with good room-temperature ductility, has rupture strength exceeding that of martensitic 12Cr-1Mo-V steel. The 14Cr-3Mo-0.5Cb-lTi-2Al steel exhibits an even higher rupture strength, but has only marginal ductility at room temperature.

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