Abstract

Prompt and delayed emissions from a naphthalene crystal doped with pyrene have been investigated in the temperature range 77–300 K. It is shown that delayed fluorescence (DF) in this crystal originates from heterofusion and homofusion of two different types of trap triplets at low temperature ( T< 130 K) and from homofusion of pyrene triplets at high temperature ( T >200 K). Pyrene concentration effects on DF suggest that free triplet excitons are trapped more efficiently at monomeric pyrene sites than at nascent excimeric pyrene sites.

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