Abstract
When pH and pMg are specified for a biochemical reaction system, thermodynamic properties are described in terms of transformed thermodynamic properties. Under these conditions, chemical reactions are written in terms of sums of species, so that the stoichiometric number matrix ν for the reaction system is replaced by an apparent stoichiometric number matrix ν' and the conservation matriix A is replaced by an apparent conservation matrix A'. The number N of specia in a biochemical reaction system may be very large because a reactant like ATP exists as an equilibrium mixture of species
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