Abstract
AbstractIn this paper, a thermodynamically consistent small strain constitutive model is formulated that is directly based on the degree of cure, a key parameter in the curing (reaction) kinetics. The new formulation is also in line with the earlier proposed hypoelastic approach, cf. Hossain et al., 2010. The curing process of polymers is a complex phenomenon involving a series of chemical reactions which transform a viscoelastic fluid into a viscoelastic solid during which the temperature, the chemistry and the mechanics are coupled. Some representative numerical examples conclude the paper and show the capability of the newly proposed constitutive formulation to capture major phenomena observed during the curing processes of polymers. (© 2013 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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