Degradation of the Three-Phase Boundary Zone of Carbon Fiber Anodes in an Electrochemical System.

Abstract

The electrochemical recycling nanoarchitectonics of graphene oxide from carbon fiber reinforced polymers (CFRPs) is a promising approach due to its economic and environmental benefits. However, the rapid degradation of the CFRP anode during the recycling process reduces its overall efficiency. Although previous studies have investigated the electrochemical oxidation of carbon fibers (CFs) and bonding of CFs to the matrix, few researchers have explicitly studied the electrochemical activity of CFs and the possible fracture caused by strong electrochemical reactions. To address this gap, this study investigates the degradation mechanism of CF anodes by analyzing changes in overall mechanical properties, hardness, elastic modulus, functional groups, and elemental composition of individual fibers. The experimental results demonstrate that the three-phase boundary region experiences the most severe degradation, primarily due to the number of oxygen-containing functional groups, which is the most important factor affecting the degree of degradation. This continuous decrease in the hardness and elastic modulus of individual fibers eventually leads to the fracture of CF anodes.