Abstract
Degradation of 13- l(S)- hydroperoxy-cis-9 , trans-11-octadecadienoic acid by a cysteine · FeCl 3 redox couple in the presence of O 2 resulted in the formation of a number of oxygenated fatty acids, among which was a novel, optically active product, trans-12,13-epoxy-11-oxo- trans-9-octadecenoic acid. A pathway for formation of the epoxyoxoene via an epoxyhydroperoxyene intermediate is proposed.
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Schedule a callMore From: Biochimica et Biophysica Acta (BBA) - Lipids and Lipid Metabolism
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