Abstract
The treatment of difficult biodegradable industrial wastewater by electrocatalytic oxidation technology has positive significance for the prevention and control of industrial pollution. In this study, particle electrode Ti–Ag/γ-Al2O3 was prepared and used as a catalyst in the 3D electrocatalytic oxidation reaction system for pretreatment of high-chemical oxygen demand (COD) concentration pesticide wastewater. Electrolysis conditions for high-COD concentration pesticide wastewater were discussed and optimized, and single-factor experiment results showed that the maximum COD removal rate was 82.50% with an energy consumption of 10.91 (kW h) kg−1 COD at conductivity of 4000 μS cm−1, current density of 30 mA cm−2, initial pH of 2.0, electrode distance of 3.0 cm, air flow of 3.0 L min−1, and filling proportion of 50.0%. The UV–visible absorption spectrum analysis of pesticide wastewater at different electrolysis times showed that the organic macromolecules containing long-chain, heterocyclic, and other structures were degraded into small molecular organic compounds. After the 3D electrocatalytic oxidation reaction, the BOD5/COD value of pesticide wastewater increased from 0.041 to 0.308, indicating that the biodegradability of the pesticide wastewater was improved significantly.
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