Abstract
The degradation of formaldehyde in a photo-Fenton reaction was studied using n-ZVI/TiO2 as the catalyst. The effects of %n-ZVI loading, catalyst dosage, H2O2, and pH on formaldehyde degradation were studied. The n-ZVI/TiO2 catalysts were prepared by impregnation with chemical reduction, and their catalytic activity was evaluated in a batch reactor under UVC light. Transmission electron microscopy (TEM) was used to determine that the n-ZVI nanoparticle size was 39.41nm. X-ray photoelectron spectroscopy (XPS) was used to study the oxidation states of 2%n‑ZVI/TiO2, and the Fe 2p spectrum of 2%n-ZVI/TiO2 indicated the presence of Fe0. The optimal conditions for the complete removal of formaldehyde within 30min were an n-ZVI loading of 2 wt.%, a catalyst dosage of 0.5g/L, 30mM H2O2, and an initial pH of 3. After the reaction, the C-H functional group of formaldehyde was not observed due to the •OH radicals generated by Fe0 and H2O2 attacking the formaldehyde molecule. Moreover, no Fe leaching was observed, presenting an advantage compared with homogeneous Fe catalysts. Therefore, 2%n‑ZVI/TiO2 shows excellent potential as a photo-Fenton catalyst for the environmentally friendly degradation of formaldehyde.
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