Abstract
The molecular weight distributions of artificially aged transformer papers were studied using SEC–MALLS with 0.5 % DMAc/LiCl as solvent, providing chain length distributions and averages. The slow dissolution and presence of non-cellulosic contaminants tend in some cases to introduce errors in the DPw estimates, and a modified data processing procedure was developed to correct for extraneous scattering. Data were compared to the intrinsic viscosities obtained in 0.5 M Cuen and the ‘viscosimetric DP’ calculated thereof according to ISO 5351. DPvisc was 2–3 times lower than the weight average DP (DPw), but closer to or slightly above the number average DP (DPn) obtained by SEC–MALLS in the case of pure cellulose. Ageing of transformer papers were in some cases associated with changes in the polydispersity (DPw/DPn). The apparent degradation rate (defined as δ(1/DP)/δt) gradually decreased with time, resulting in a tendency for a ‘level-off’ DP in the range 200–300 for DPvisc and DPn, and roughly 1,000 for DPw.
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