Degradation of aromatic amines in textile-dyeing sludge by combining the ultrasound technique with potassium permanganate treatment

Abstract

This paper reports, for the first time, a combined technique of ultrasound (US) with KMnO4 degradation of aromatic amines in a textile-dyeing sludge. The reaction mechanisms and the degradation kinetics of aromatic amines at various operating parameters (KMnO4 dosage, US power density and pH) were systematically examined by the combined system of US-KMnO4. The results indicated that there was a synergistic effect between US and KMnO4, as US greatly enhanced KMnO4 in the degradation of aromatic amines and exhibited apparent sludge disintegration and separated pollutants from the sludge. In addition to accelerating the Mn(VII) reaction with pollutants in the filtrate, US also caused Mn(VII) to enter the porous sludge and sufficiently facilitated the reaction of the strongly absorbed aromatic amines. The combined treatment of US-KMnO4 was effective in the degradation of aromatic amines in textile-dyeing sludge. On average, 58.7% of monocyclic anilines, 88.3% of other forms of aromatic amines, and 24.0% of TOC were removed under the optimal operating conditions of a KMnO4 dosage of 12mM, an US power density of 1.80W/cm3 and pH 5. The present study proposed US-KMnO4 treatment as a practical method for the disposal of aromatic amines in textile-dyeing sludge.