Degradation and Detoxification of Remazol Blue Contaminants as a Model Textile Effluent via Advanced Nonthermal Plasma Oxidation Processes

Abstract

This study explores the degradation of the reactive Remazol Blue RR (RBRR) as a model textile effluent upon its exposure to non-thermal atmospheric pressure plasma. An extensive comparative study of different combinations of the following plasma/solution treatment environments was conducted: 1) Ar plasma jet (Ar-PJ) alone; 2) Ar/O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> and Ar/N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> plasmas; 3) Ar plasma with O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> or N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> injected (INJ) in the bulk of the Ar plasma afterglow; and 4) Ar plasma with O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> or N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> bubbling (BB) in the RBRR solution. In all conditions, plasma treatment was carried out at a fixed applied voltage of 31 kV and treatment time of 10 min. The degradation efficiency of RBRR in the different plasma-treated solutions was evaluated using UV–visible spectroscopy. Optical emission spectroscopy (OES) was used to examine the generation of excited species in plasma during the degradation processes. Moreover, the concentration of plasma-induced reactive hydroxyl radicals (OH <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">•</sup> ) and hydrogen peroxide (H <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> ) was determined spectroscopically. To further corroborate the results, the pH, conductivity, and total organic carbon (TOC) of the plasma-treated RBRR solutions were assessed. Overall, the results showed that the highest degradation efficiency (45%) was obtained upon exposure of RBRR aqueous solution to Ar plasma with N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> bubbling in the solution. The non-toxic nature of all plasma-treated solutions was confirmed by non-inhibition of bacterial growth ( <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">Escherichia coli</i> and <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">Staphylococcus aureus</i> ). Overall, plasma treatment in general and Ar plasma accompanied with N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> bubbling in particular constitute an eco-friendly and very promising techniques to degrade/decolorize textile effluent.