Abstract

C 34 -Botryococcene, the major hydrocarbon constituent of the B race of Botryococcus braunii, was degraded by ozonolysis of its dihydro derivative followed by Baeyer-Villiger oxidation to γ-valerolactone, 2,5-dimethyl-hexanolactone, and 2-ethyl-2,5-dimethylhexanolactone. These three lactones were correlated with enantiomerillacy pure, synthesized materials using a progressive induced chemical shift technique with the chiral shift Eu(hfc) 3

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