Abstract
The coherent Raman spectra of electrically discharged 14N2 and 15N2 were analysed using the deformationally self-consistent procedure for the treatment of spectral data. By making use of eight independent unconstrained parameters, 356 measured spectral lines were reproduced with σ = 0.0023 cm−1, and F = 8.74 × 1013. From a marginally evaluated value of the parameter tN0, related to non-adiabatic rotational effects, we predicted a rough value of the rotational g-factor for 15N2 g0 = −0.37(21), near the known experimental value g0 = −0.2593(5). Fit with the constrained tN0 yielded σ = 0.0023 cm−1, , F = 1.00× 1014, and the set of seven well evaluated parameters representing the Born–Oppenheimer potential energy function and non-adiabatic vibrational effects. Copyright © 1999 John Wiley & Sons, Ltd.
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