Abstract
The deformable-body model and a deformational self-consistent procedure are applied in the quantitative analysis of adiabatic and nonadiabatic effects in the vibration–rotational spectra of GaHX1Σ+. By making use of 18 independent unconstrained parameters 1094 vibration–rotational transitions of69Ga1H,71Ga1H,69Ga2H, and71Ga2H have been reproduced with σ = 0.000168 cm−1,σ̂= 1.087, andF= 1.017 × 1016. The molecular rotationalg-factor and electric dipole moment were evaluated from spectra without application of Stark and Zeeman techniques. The mass andJdependence of the electric dipole moment and the effect of a rotationally induced reversal of polarity+GaH−→−GaH+in excited rotational states are discussed.
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