Deformation and failure mechanisms in graphene oxide paper using in situ nanomechanical tensile testing

Abstract

Graphene oxide (GO) paper is a promising candidate for novel applications in energy storage systems such as electrical batteries, supercapacitors and multi-layered composites where the material undergoes deformation mechanisms. In particular, the strength of graphene oxide paper is critical in such applications and is defined by the interaction between the GO sheet constituents of the paper. The deformation behavior and tensile strength of focused ion beam (FIB) fabricated GO micro-beams was measured using in situ atomic force microscopy (AFM). GO sample deformation and failure was dependent on both the size of the micro-beams and the environmental testing conditions. Specifically, the failure stress of GO paper micro-beams tensile tested in air was found to increase when compared to testing in vacuum. This environmental dependent tensile strength of GO paper is attributed to water promoting stress transfer between GO sheets within the paper for higher strength during air testing while vacuum conditions remove water, leading to poor stress transfer between GO sheets for lower tensile strength results. A two-parameter Weibull distribution is introduced to quantify the micro-beam size dependent strength, which is attributed to interfacial defects determining GO paper failure strength.