Abstract
AbstractThe deviation from stoichiometry δ in hausmannite (Mn3δO4) has been thermogravimetrically studied as a function of oxygen activity between 1000 and 1130°C for the low temperature phase (α‐Mn3δO4) and between 1200 and 1350°C for the high temperature phase (ß‐Mn3δO4). A cation deficit is observed at high oxygen activities and a cation excess at low oxygen activities. In the temperature range investigated, it is concluded that the dominant defect species in both phases are cation vacancies at high oxygen activities and manganese interstitials at low oxygen activities. In addition, based on the present nonstoichiometry data, the phase diagram of the maganese‐oxygen
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Berichte der Bunsengesellschaft für physikalische Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
