Defect-induced fracture topologies in Al2O3 ceramic-graphene nanocomposites

Abstract

Models of ceramic-graphene nanocomposites are used to study how the manufacturing process-dependent arrangement of reduced graphene oxide (rGO) inclusions governs nano-crack network development. The work builds upon recent studies of such composites where a novel combinatorial approach was used to investigate the effect of rGO arrangements on electrical conductivity and porosity. This approach considers explicitly the discrete structure of the composite and represents it as a collection of entities of different dimensions - grains, grain boundaries, triple junctions, and quadruple points. Here, the combinatorial approach is developed further by considering the effects of rGO agglomerations, stress concentrators and adhesion energies on intergranular cracking. The results show that the fracture networks can be effectively controlled by the local ordering of rGO inclusions to allow for a concurrent increase in the strength and conductivity of the ceramic composites. It is shown that the ratio of local stress concentrators related to rGO inclusions and cracks is the most significant factor affecting the nano-crack network topology. The local spatial arrangement of rGO inclusions becomes an effective tool for controlling nano-crack network topology only when this ratio approaches one. It is anticipated that these results will inform future design of toughness-enhanced composites.