Deep ultraviolet spontaneous emission enhanced by layer dependent black phosphorus plasmonics.

Abstract

Although graphene has been the primary material of interest recently for spontaneous emission engineering through the Purcell effect, it features isotropic and thickness-independent optical properties. In contrast, the optical properties of black Phosphorus (BP) are in-plane anisotropic; which supports plasmonic modes and are thickness-dependent, offering an additional degree of freedom for control. Here we investigate how the anisotropy and thickness of BP affect spontaneous emission from a Hydrogenic emitter. We find that the spontaneous emission enhancement rate i.e. Purcell factor (PF) depends on emitter orientation, and PF at a particular frequency and distance can be controlled by BP thickness. At lower frequencies, PF increases with increasing thickness due to infrared (IR) plasmons, which then enhances visible and UV far-field spectra, even at energies greater than 10 eV. By leveraging the thickness and distance-dependent PF, deep UV emission can be switched between 103 nm or 122 nm wavelength from a Hydrogenic emitter. Additionally, we find that doping can significantly tune the PF near BP and this alteration depends on the thickness of the BP. Our work shows that BP is a promising platform for studying strong plasmon-induced light-matter interactions tunable by varying doping levels, emitter orientation, and thickness.