Abstract

The solubility of CO2 in a hydrophilic and a hydrophobic deep eutectic solvent (DES) has been measured at pressures up to 2 MPa and a temperature of 308.15 K. The CO2 solubility was found to be much higher in the hydrophobic DES than in the hydrophilic DES. Both DESs could be repeatedly used as absorbing agents without losing absorption capacity. Thus, the DESs do not react among themselves and the CO2 absorption process is fully reversible. The results were also compared to solubility data with ionic liquids (ILs) and currently applied physical solvents. The measured CO2 solubilities in the best performing (hydrophobic) DES were found to be similar to those in fluorinated ILs, which are known for their high CO2 capture capability, but are much more expensive and less environmentally benign than the hydrophobic DES studied in this work. Moreover, the values are very close to that of Selexol, the current industrial standard for physical CO2. absorption. Thus, hydrophobic DESs are a promising alternative class of CO2 capture media.

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