Abstract

Metal–semiconductor contacts are used to examine deep electronic states near the (In,Ga)P surface by deep-level transient Fourier spectroscopy. Towards the as-grown (In,Ga)P surface, the In mole fraction increases due to parasitic indium deposited from the horizontal reactor during cooling after growth. This process is accompanied by compressive strain, which leads to the formation of several deep-level defects near the surface of Si- as well as Zn-doped (In,Ga)P layers and their successive diffusion into the epitaxial layer. In contrast, Si-doped (In,Ga)P capped by a GaAs layer is practically free of deep-level defects. In the bulk of Zn-doped layers, a dominant hole trap is found at 0.91eV with or without a GaAs cap layer.

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