Abstract

Trivalent phosphorus compounds, triphenylphosphine and triethyl phosphite, gave rise to dediazoniation of an arenediazonium salt in alcoholic solvent at ambient temperature in the dark. The reaction was well interpreted in terms of radical-chain mechanism initiated by an electron transfer from the trivalent phosphorus to a diazonium salt, which postulates a cation radical from the trivalent phosphorus as an intermediate.

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