Decontamination of Cs from Japanese cedar (Cryptomeria japonica) via kraft cooking

Abstract

To investigate the possibility of decontaminating 137Cs-contaminated Cryptomeria japonica wood, kraft pulping was conducted and the Cs behavior in the reaction process was examined. 133Cs-treated or 137Cs-contaminated bark, sapwood, and heartwood chips of Cryptomeria japonica were digested using an aqueous solution of NaOH and Na2S. The pulp was washed with ultrapure water and filtered, after which the filtrate (black liquor) was collected. The black liquor was acidified to separate the supernatant and precipitation. The Cs (133Cs and 137Cs) concentrations in the chip and reaction products were measured. As for wood samples, the majority of Cs was present in black liquor, while only a minor amount of Cs was retained in the pulp (<1%). In the case of bark, although the majority of Cs was present in the black liquor, the proportion of Cs in the pulp was much higher than that in the wood pulp. In addition, the Cs in the precipitation of the bark was higher than that in the wood, possibly because the Cs in the bark was combined with some components, which is insoluble in alkaline solution. Our results suggest that 137Cs-contaminated Cryptomeria japonica wood can be used in the pulp and paper industries.