Decomposition of dilute trichloroethylene by nonthermal plasma

Abstract

Decomposition performance of a dilute toxic organic compound, trichloroethylene (TCE), in air by using nonthermal plasma processing was studied extensively. The nonthermal plasma was generated by the high-frequency (2 kHz) or commercial-frequency (50 Hz) barrier discharge in a fused silica tube. Three types of reactors, bolt type, rod type (both are barrier-discharge type), and coil type (surface-discharge type), were tested. Analysis of byproducts, residual materials, and end products generated by the plasma process was performed by a gas chromatography mass spectrometer or gas chromatography. Most organic byproducts decrease with an increase of the electric discharge power, but only toxic phosgene increases with the increase of the discharge power. As a post process, NaOH solution was used to test effluent from the plasma reactor. The solution was found effective in phosgene absorption. Comparison between nonthermal plasma and UV irradiation for TCE decomposition was also made. In regard to the energy efficiency of TCE decomposition, UV irradiation is found much better than discharge plasma.