Deciphering the Kinetic Study of Sodium Dodecyl Sulfate on Ag Nanoparticle Synthesis Using Cassia siamea Flower Extract as a Reducing Agent.

Abstract

Silver nanoparticles (Ag NPs) were synthesized using Cassia siamea flower petal extract (CSFE) as a reducing agent for the first time. In its presence and absence, the correlative effects of the anionic surface-active agent sodium dodecyl sulfate (SDS) were studied with respect to the development and texture of Ag NPs. Under different reagent compositions, the Ag NPs were inferred by localized surface plasmon resonance peaks between 419 and 455 nm. In the absence of SDS, there was a small eminence at 290 and around 350 nm, pointing toward the possibility of irregular polytope Ag NPs, which was confirmed in the transmission electron microscopy images. This elevation vanished beyond the cmc of [SDS], resulting in spherical and oval shaped Ag NPs. The effects of reagent concentrations were studied at 25 °C and around 7 and 9 pH in the absence and presence of SDS, respectively. Also, kinetic studies were performed by UV–visible spectrophotometry. Prodigious effects on shape and size were found under different synthesis conditions in terms of hexagonal, rod-, irregular-, and spherical shaped Ag NPs. Furthermore, the antimycotic activity of the synthesized Ag NPs was established on different Candida strains, and best results were found pertaining Candida tropicalis. The ensuing study impels the control of texture and dispersity for Ag NPs by CSFE and SDS, and the resultant polytope Ag NPs could be a future solution for drug-resistant pathogenic fungi.