Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst

Abstract

A low cost catalyst prepared by pyrolyzing electrode coating material from spent Li-ion battery cells was shown as an effective catalyst for the decarboxylative - dimerization of levulinic acid to a mixture of C6 and C9 fuel precursors. The highest levulinic acid conversion of 94% was observed with 10% (w/w) catalyst loading under 1.24 MPa H2 at 140 °C, 15 h. A reaction scheme was proposed to explain the novel transformation producing C9 lactone products and C6 unsaturated alcohol product through a decarboxylative pathway followed by the aldol dimerization of levulinic acid.