Abstract
Abstract Diphenylbismuth carboxylates Ph2BiX (X = OAc = CH3COO, C2H5COO, C3H7COO, Me2CHCOO, Me3CCOO, CH3COCH2CH2COO, PhCOO; Me = CH3; Ph = C6H5) have been prepared from Ph2BiCl and NaX or from Ph2BiOC2H5 and HX in anhydrous ethanol. PhoBiOAc and a compound of approximate composition PhBi(OAc)2 have been obtained in small yields from acidolysis of Ph3Bi with HOAc (molar ratio 1:1 and 1:3, resp.) in acetone. A polymeric structure with bridging bidentate carboxylate groups is proposed for Ph2BiX compounds.
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