Abstract
Abstract Phenylthio substituted oligosilanes are obtained from the reaction of oligomeric silicon halides with alkali metal thiophenolates M1SPh (MI = Li, Na, K). Si—Si bonds are formed when phenylthiooli-gosilanes are reacted with alkali metal silicon compounds. Alkali metal thiophenolates, the second reaction products can be separated easily. Quite similarly, Fe—Si-bonds are obtained from phenyl-thiosilanes and Na[Fe(CO)2Cp]. In contrast to the related alkali metal halide elimination reactions of organohalooligosilanes, transmetallations are never observed in the thiophenolate reactions.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Phosphorus Sulfur and Silicon and the Related Elements
Paper Title
Journal
Date
