Abstract
Metal–Containing Heterocycles: Preparation, Properties and Reactions, LXXIX[1a]. – Synthesis of a Diphosphamangana–cyclopentene by Alkyne Insertion into the Mn–P Bond of a DiphosphamanganacyclopropaneInsertion of the alkyne ZCCZ with ZCO2Me into the Mn–P bond of the diphosphamanganacyclopropane results in the formation of the thermally and kinetically stable diphosphamanganacyclopentene (2). According to an X–ray structural analysis 2 crystallizes in the orthorhombic space group P212121 with Z 4.
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