Abstract

Preparation and Properties of Hexasubstituted BenzenesHexasubstituted benzenes are of potential interests as polypodands, host molecules and disc‐like molecules. They are prepared by catalytic cyclotrimerization of disubstituted alkynes 1–8 or by nucleophilic substitution of bromine in hexakis (bromomethyl)benzene 9–17. The different methods of preparation were compared. The new hexasubstituted benzenes were characterized by some chemical and physical properties.

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