Darstellung stabiler Phosphor-Heterofullerene im Hochfrequenzofen

Abstract

Generation of Stable Phosphorus Heterofullerenes in a Radiofrequency Furnace For the first time, phosphorus heterofullerenes, mainly C59P and C69P have been produced, and identified by mass spectroscopy. Their chemical properties have been characterized with respect to their behaviour at sublimation as well as to solubility and to sensivity to air. The formation of these heterofullerenes was achieved by evaporating phosphorus and carbon simultaneously, however, at different positions, that is at different temperatures, in a radiofrequency furnace.