Abstract

To study the relationship between donor (D)-acceptor (A) structures and the third-order nonlinear optical property, two types of D-A and D-A-D structures based on triphenylamine-substituted chromophores with benzanthrone or perylene diimide (PDI) acceptors have been designed and synthesized. Among them, D-A-D type chromophores with a linear configuration show relatively larger two-photon absorption (2PA) coefficient and 2PA cross section value.

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