Abstract
A slight D 3 d distortion on the octahedral UF 6 − complex splits the Γ ' 8 and Γ 8 octahedral levels into four doublets. These doublets and other electronic levels of the CsUF 6 ground configuration have been identified according to their vibronic side-bands. In the calculation of the crystal field Hamiltonian, the amount of D 3 d distortion on the UF 6 − octahedron is treated as the parameter, Δ. The interactions of the 5 f electron of the UF 6 − complex contains five parameters: ξ 5 f , B 2 0, B 4 0, B 6 0 and Δ. The calculated energy spectrum and the g-tensor of the ground state show good agreement with the experimental measurements.
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