Abstract

AbstractA linear high polymer composed of repeating α‐methylene glutaric anhydride units has resulted from the controlled cyclopolymerization of acrylic anhydride. Proof for the linear nature of this polymer is based upon solubility and thermoplastic behavior. Proof for the cyclic nature of the polymer is based upon the lack of residual unsaturation. The molecular weight of linear polyacrylic anhydride has been altered by the use of chemical modifying agents in the polymerization recipe. Linear polyacrylic anhydride undergoes characteristic carboxylic anhydride reactions.

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