Cyclodextrin incorporated textile supercapacitor/piezo-triboelectric nanogenerator hybrid system for versatile temperature dependent wearable wireless devices

Abstract

The problem of wearable textile electronics having no power source can be greatly assisted at low-temperature environments by the demand for flexible supercapacitor sustaining self-charging system. We explore a typical piezo-triboelectric nanogenerators (PTNGs) textile fabric integrated flexible supercapacitors (SCs) face substantial difficulty in maintaining their ability to quickly charge in colder environments for various wearable wireless sensing devices. PTNGs using composite electrodes frequently experience quick performance degradation at low energy levels as a result of the poor ion mobility besides charge transfer in the electrolyte. In this article, we offer a SC-coupled self-chargeable power generator with wide operating temperature range (25 ∼ −80 °C). A composite system of sulfonated β-cyclodextrin/polyvinylpyrrolidone/Ni@MnCO3 on cotton fabric with polyvinylidene fluoride and polydimethylsiloxane were used to build the smart textile SC, which produced 19.6 V at −80 °C and exhibited a gravimetric capacitance of 94.7 Fg−1 with excellent cyclic stability (>50,000). The biocompatibility studies reveal good results (∼95 % of cell viability) for the wearable textile SCs. In addition, the possibility of application to a sensing device was successfully demonstrated by connecting the proposed self-driving energy storage complex to a device designed as a wireless circuit. This system can work for seamlessly working for wireless signal transmittance as power source resulting and this system may be able to meet the urgent need for wearable electronics that implanted in the space suit and/or winter clothing needed in harsh climates.