Abstract
Course of cyclization of dienols, polyenes, and dienyne mediated by mercuric salts were controlled by stability of cationic intermediates and source of mercuric salts. Reaction of ( E)-5,9-dimethyl-4,8-decadiene-1-ol with mercuric acetate gave the intramolecular oxymercuration product, whereas one with mercuric triflate produced the olefin cyclization products.
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