Cyclic voltammetry study of the electrochemical behavior of vanadyl sulfate in absence and presence of antibiotic

Abstract

The cyclic voltammetry technique was used to study the electrochemical behavior of vanadyl sulfate in absence and presence of antibiotic (cefazolin) in 0.1 M KCl under different pH values at 300.15 K. The redox behavior of vanadyl sulfate has been studied by using glassy carbon electrode, Ag/AgCl as a reference electrode and Pt wire as a counter electrode under potential from +1500 mV to −1000 mV. One anodic peak and one cathodic peak are observed in cyclic voltammograms. Peak current ratio and peak potential separation (ΔE) was calculated, the higher values of them gave an indication about systems under study are quasi-reversible. The effect of pH, scan rate and concentration of electroactive species on the interaction between vanadyl sulfate and antibiotic were studied. Charge transfer coefficients (α), the heterogeneous electron transfer rate constants (ks) and the diffusion coefficients (D) involved in the redox reaction were evaluated.